全文获取类型
收费全文 | 13540篇 |
免费 | 1251篇 |
国内免费 | 9篇 |
专业分类
电工技术 | 87篇 |
综合类 | 9篇 |
化学工业 | 4792篇 |
金属工艺 | 138篇 |
机械仪表 | 318篇 |
建筑科学 | 548篇 |
矿业工程 | 23篇 |
能源动力 | 352篇 |
轻工业 | 3714篇 |
水利工程 | 127篇 |
石油天然气 | 85篇 |
无线电 | 543篇 |
一般工业技术 | 1956篇 |
冶金工业 | 715篇 |
原子能技术 | 41篇 |
自动化技术 | 1352篇 |
出版年
2024年 | 32篇 |
2023年 | 135篇 |
2022年 | 151篇 |
2021年 | 1114篇 |
2020年 | 464篇 |
2019年 | 467篇 |
2018年 | 532篇 |
2017年 | 559篇 |
2016年 | 609篇 |
2015年 | 501篇 |
2014年 | 656篇 |
2013年 | 1017篇 |
2012年 | 947篇 |
2011年 | 1109篇 |
2010年 | 822篇 |
2009年 | 784篇 |
2008年 | 719篇 |
2007年 | 678篇 |
2006年 | 519篇 |
2005年 | 399篇 |
2004年 | 339篇 |
2003年 | 314篇 |
2002年 | 285篇 |
2001年 | 168篇 |
2000年 | 112篇 |
1999年 | 151篇 |
1998年 | 132篇 |
1997年 | 136篇 |
1996年 | 96篇 |
1995年 | 89篇 |
1994年 | 80篇 |
1993年 | 75篇 |
1992年 | 75篇 |
1991年 | 50篇 |
1990年 | 42篇 |
1989年 | 41篇 |
1988年 | 41篇 |
1987年 | 30篇 |
1986年 | 44篇 |
1985年 | 39篇 |
1984年 | 30篇 |
1983年 | 31篇 |
1982年 | 21篇 |
1981年 | 19篇 |
1980年 | 20篇 |
1979年 | 22篇 |
1978年 | 23篇 |
1977年 | 21篇 |
1976年 | 8篇 |
1975年 | 13篇 |
排序方式: 共有10000条查询结果,搜索用时 203 毫秒
91.
Maria E. Amato Antonio Grassi Kenny B. Lipkowitz Giuseppe M. Lombardo Giuseppe C. Pappalardo Claudia Sadun 《Journal of Inorganic and Organometallic Polymers and Materials》1996,6(3):237-253
Suitable parameter sets for the CHARMm force field were derived for the structural units in polychlorophosphazene [P=N, P N, P Cl] using the Dinur Hagler energy second derivative procedure based on quantum mechanical SCI calculations using the 6–31G* basis set. To validate the reliability of the parameter set, structural results obtained with CHARMm for the adopted model compounds (OP2NCl5 and OP3N2Cl5) were compared with those derived fromab initio quantum mechanics using the 6–31G* basis set. Application of molecular dynamics (MD) simulations in combinatioin with the available X-ray diffraction data provided structural and conformational information on the polymer. The calculation made using the periodic boundary conditions (PBC) agree well with the polychlorophosphazene ordered in a monoclinic unit cell (a=5.98,b=12.99,c=4.92 A; β=111.7). This model was stabilized mainly by the image atoms contribution to the electrostatic energy term and had aquasi-planar conformation of the backbone chain (glide symmetry). The MD calculations also provided evidence that the difference between single and double PN bonds is less marked than that measured experimentally. This result is, however, in agreement with more recent and accurate X-ray studies on poly(methylphosphazene). Validation of the polymer model provided a complete picture, otherwise experimentally inaccessible, of the internal fluctuations of the polymeric chains. 相似文献
92.
The bulk modification of SBS rubber with maleic anhydride in a mixing chamber of a Haake rheomixer was studied. The effect of temperature, maleic anhydride, and benzoyl peroxide concentrations on the grafting efficiency was evaluated. High grafting efficiency was achieved when the ratio of peroxide and maleic anhydride concentration was high. On the other hand, on this condition high insoluble fraction was generated. The addition of a diamine, 4,4′‐diaminediphenylmethane to the reaction mixture minimizes the amount of insoluble polymer. However, the grafted MAH content also decreases. The graft copolymer was characterized by infrared spectroscopy and the grafting extension was determined by titration. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 2953–2960, 2002; DOI 10.1002/app.10355 相似文献
93.
94.
Ionomeric composites based on sepiolite and hydrogenated poly(styrene butadiene) block copolymer were obtained and characterized from a microstructural and electrical point of view. Before blending, because of the high silanol group concentration in the sepiolite, the latter could be organophilized with suitable coupling agents. The resulting materials were easily processed into thin films or membranes 0.2–0.4 mm thick, their conductivity in some cases approaching 10?1 S/cm. Their suitability for film formation and good electrical properties indicate potential applications as electrolytes in polymer fuel cells. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 3512–3519, 2002 相似文献
95.
P Casolo D Mosca C Amorotti B Drei A Raspadori P Di Blasio E Ganz G De Luca G Colli R De Maria D Amuso 《Canadian Metallurgical Quarterly》1997,68(2):207-11; discussion 212
Primary and sole breast lymphoma is a very rare disease. With the review of our series of 616 cases operated on for breast cancer, only 3 cases (0.48%) of primary breast non-Hodgkin lymphoma (LNH) have been observed. The authors outline the problems concerning diagnosis and therapy of this rare disease: pathological and immunohistochemical aspects are discussed. They stress the importance of staging in order to plan a correct multidisciplinary approach. 相似文献
96.
97.
Teresa A Morrison J Raymond Kessler Ronald D Hatfield Dwayne R Buxton 《Journal of the science of food and agriculture》1994,65(2):133-139
To ascertain the temporal relationships of phcnylpropanoid and lignin pathway enzymes, phenylalanine ammonia-lyase (PAL) and cinnamyl alcohol- NADPH dehydrogenase(CAD), with lignin concentration, PAL and CAD activities and lignin concentrations were assessed during progressive development of the 10th internode in maize (Zea mays L). Enzyme activities were quantified and lignin concentrations were determined by the detergent system of fiber fractiona- tion from lower, middle, and upper sections of the elongating internode harvested 3, 5, 7, 9, 11, 13, and 15 days after the internode had reached 10 mm in length. Over 15 days, a coordinated, sequential, and basipetal pattern of enzyme activities and lignin accumulation evolved through the internode, spanning the stages of rapid elongation, cellular differentiation, and secondary cell wall formation. PAL activity was initiated first, rising to peak activity in elongating tissue, and falling basipetally in tissues as they matured. CAD activity rose in fully elongated, maturing internode tissue where PAL activity was waning following its peak activity. Lignin accumulated in tissues with high CAD activity. CAD activity and lignin deposition patterns were similar: simultaneously increasing in activity and deposition over time while activity and deposition also shifting basipetally through the internode, keeping pace with secondary cell wall formation. Lignin concentration correlated significantly with CAD, but not with PAL. 相似文献
98.
Juntunen Cindy L.; Atkinson Donald R.; Reyes Carla; Gutierrez Maria 《Canadian Metallurgical Quarterly》1994,31(2):327
Investigated whether (1) feminist identity development for women therapists was related to their use of feminist therapy behaviors (FTBs) and (2) feminist identity development and use of FTBs for women therapists were related to self-identification as a feminist therapist. 153 women psychologists (aged 30–77 yrs) were administered a women's issues in therapy questionnaire, which included a short version of the Feminist Identity Scale (FIS; K. M. Rickard, 1989, 1990). Ss were categorized into stages of feminine identity development according to their scores on 4 subscales of the FIS: Passive-Acceptance (PA), Revelation (REV), Embeddedness (EMB), and Synthesis (SYN). Ss scoring high on SYN and REV, and low on PA, reported greater use of FTBs; scores on the EMB were not related to the use of FTBs. All 4 subscales were predictive of women therapists who self-identified as feminist therapists. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
99.
Sandra Aparecida de Assis Pedro Fernandes Bruno Sommer Ferreira Joaquim MS Cabral Olga Maria Mascarenhas Faria Oliveira 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2004,79(3):277-280
A partially purified extract of pectinmethylesterase (PME) from acerola fruit was immobilized on various supports: glass, celite, chrysotile, agarose, concanavalin A Sepharose 4B, egg shell, polyacrylamide and gelatin. In addition, reticulation with glutaraldehyde was assessed, as well as the use of gelatin in the presence of celite, glass and silica. The highest immobilization yields were obtained when the pectinmethylesterase was immobilized in concanavalin A Sepharose 4B (81.7%) and in gelatin‐water (78.0%). Copyright © 2004 Society of Chemical Industry 相似文献
100.
Molecular model systems based on propyl phosphonic acid (ppa) were studied by means of density functional theory calculations in order to describe the acid-acid interaction and the formation of the hydration sphere. The formation of ppa dimers is reported and the energetic difference between two dimer structures is presented. The hydration sphere of ppa was represented by model systems ppa(H2O)n, for which the system with n=4 formed the first hydration sphere (h1), while n=7 can be considered a good approximation to the complete inner hydration sphere around the phosphonic acid group. The study of the ppa-H+ (H2O)n model systems showed an interesting structural behavior comparatively to the ppa(H2O)n systems. The protonated acids exhibited equivalent phosphorous-oxygen bonds and a general molecular structure is proposed to represent these protonated species. 相似文献